Proof of Liouville's Theorem
We prove that Hamiltonian flows preserve the Liouville volume form .
Setup: Let be a -dimensional symplectic manifold, a Hamiltonian function, and the flow of the Hamiltonian vector field defined by .
Step 1: Hamiltonian vector fields preserve
By Cartan's formula:
Since and (closedness), we have:
Thus preserves : .
Step 2: Preservation extends to
We need to show . Using the derivation property of the Lie derivative:
Since is a derivation on forms:
By Step 1, , so:
Proceeding inductively, if , then .
The base case is from Step 1. Therefore for all .
Step 3: Integration yields flow preservation
The Lie derivative measures the infinitesimal change along the flow:
If , then:
Integrating from to :
Since , we have , completing the proof.
The key insight is that preservation of by automatically implies preservation of . This is a special feature of Hamiltonian vector fields: they preserve not just volume, but the entire symplectic structure.
In local coordinates , the Hamiltonian vector field is:
The divergence with respect to the volume form is:
The mixed partials cancel by equality of mixed partials, so is divergence-free.
For on :
The flow is , a rotation.
For any region :
Computing the pullback:
Thus area is preserved.
Alternative proof via Jacobian: If is the Hamiltonian flow, its Jacobian matrix satisfies:
for all . This follows from the fact that at each point, and symplectic matrices have determinant 1.
The volume element transforms as:
In statistical mechanics, the phase space density evolves according to Liouville's equation:
This is equivalent to , i.e., is constant along Hamiltonian flow. Combined with volume preservation, this gives the conservation of the measure .